Transformation of Thiolatogold(I) to an Au Complex with an (Arylthio)silyl Ligand. Use of an (Aminosilyl)boronic Ester as a Silylene Precursor

Yoshitaka Tsuchido,Kazuki Okuma,Tomohito Ide,Kohtaro Osakada

doi:10.1021/acs.organomet.0c00294

Transformation of Thiolatogold(I) to an Au Complex with an (Arylthio)silyl Ligand. Use of an (Aminosilyl)boronic Ester as a Silylene Precursor

Yoshitaka Tsuchido, Kazuki Okuma + Show 2 more

https://doi.org/10.1021/acs.organomet.0c00294

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Journal: Organometallics	Publication Date: Jul 6, 2020
Citations: 6

Affiliation: Life Science Institute, Tokyo Institute of Technology, National Institute of Technology, Tokyo College

#Silyl Ligand #Boronic Ester + Show 3 more

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Abstract

The gold(I) thiolate complex [Au(SC6H4-4-OMe)(PCy3)] reacts with an (aminosilyl)boronic ester, Et2N-SiPh2-BO(CMe2)2O, to afford a complex with an (arylthio)silyl ligand, [Au(SiPh2(SC6H4-4-OMe))(PCy...

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