Transformation of spin-orbit excited states of halogen atoms in the chemical reactions F + Br 2 → BrF + Br, I *+ Br 2 → IBr + Br, and Br + IBr → Br 2 + I

E.B Gordon,A.I Nadkhin,S.A Sotnichenko,I.A Boriev

doi:10.1016/0009-2614(82)83271-5

Transformation of spin-orbit excited states of halogen atoms in the chemical reactions F + Br 2 → BrF + Br, I *+ Br 2 → IBr + Br, and Br + IBr → Br 2 + I

E.B Gordon, A.I Nadkhin + Show 2 more

https://doi.org/10.1016/0009-2614(82)83271-5

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Journal: Chemical Physics Letters	Publication Date: Feb 1, 1982
Citations: 17

#Spin-orbit Excited State #States Of Atoms + Show 8 more

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Abstract

The small laser pulse gain method, based on photochemical Br and I lasers, is used to probe 2P 3/2 and 2P 1/2 states of iodine and bromine atoms in the reactions F + Br 2 → BrF + Br (I), I( 2P 1/2) + Br 2 → IBr + Br (II), and Br + IBr → Br 2 + I (III). The results obtained are capable of formulating a conservation rule for the spin-orbit excited state.

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