Abstract

The reactivity of CCl 4 with pyrite was investigated by measuring the CCl 4 transformation rates and products under aerobic and anaerobic conditions. Under all reaction conditions, >90% of the CCl 4 was transformed within 12-36 days in the presence of 1.2-1.4 m 2 /L pyrite at 25 o C. A zero-order dependence on the CCl 4 concentration supports a surface-controlled reaction mechanism wherein the rate of reaction depends on the absorbed CCl 4 concentration

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