Abstract
A monomeric iron Fe(η2-N2H3) species has been prepared, and exposure to oxygen yields a diiron complex that features five-coordinate iron centers and an activated bridging diazene ligand (NH=NH). Combined structural, theoretical, and spectroscopic data for the redox pair of complexes [Fe2(μ-N2H2)]2+/1+ are consistent with 4-center, 4-electron π-delocalized bonding picture across the Fe-NH-NH-Fe core that finds analogy in butadiene and the butadiene anion.
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