Transformation from Knudsen diffusion to facilitated diffusion for CO2 in confined mass transfer channels of polyimide mixed matrix membranes

Abstract

Incorporation of porous materials in a polymeric membrane is an effective strategy for improving the gas permeability of the resulting mixed matrix membranes (MMMs). However, effective improvement of selectivity of membrane toward CO2 separation is still a significant challenge due to the insufficient CO2 capture performance of porous materials. In this study, polyimide (PI)-based MMMs with enhanced CO2 capture performance were prepared for CO2 separation. First, an ionic liquid (IL) with a high affinity for CO2 was immobilized in the inner pore structures of two types of mesoporous silica (SiO2) molecules to form IL@SiO2 composites. These composites were used as nanofillers to construct the MMMs. The stable immobilization of IL inside the pores of the mesoporous SiO2 indicated that the IL@SiO2 and MMMs both exhibited higher adsorption selectivity for CO2. The gas solubility coefficient of the MMMs was positively proportional to their maximum gas adsorption capacity, which was determined by the gas adsorption capacity of the PI polymer and nanofillers. More interestingly, the diffusion coefficients of different gases in the MMMs were closely related to the confined mass transfer channels introduced by the nanofillers. The diffusion of CO2 in the confined mass transfer channels of MMMs was facilitated and N2 diffusion was slightly inhibited, which increased the diffusion selectivity of the resulting MMMs for CO2. Combined with Maxwell–Wagner–Sillar model calculations for gas permeation, it was confirmed that IL immobilization transformed the diffusion mode of CO2 in the confined mass transfer channels of the MMMs from Knudsen diffusion to facilitated diffusion. However, the immobilization of excessive ILs in the mesopores blocked the mass transfer channels of the MMMs, resulting in lower gas permeability and decreased CO2 separation selectivity.