Transformation and environmental chemical characteristics of hazardous trace elements in an 800 t/d waste incineration thermal power plant

Abstract

The hazardous trace elements (HTEs) emitted during the municipal solid waste incineration (MSWI) process have been widely concerned. In this work, the bottom ash (BA), heat recovery boiler ash (HA), and ash after desulfurization (SA) were collected to explore the occurrence forms of HTEs in the three types of ash and their relationship with minerals and leaching characteristics. The results show that the volatility of the seven studied HTEs follows the order of Cd, As > Ni, Zn > Pb > Cr, Cu. In the process of BA → HA → SA, the content of Cd, As, Zn, and Pb shows an increasing trend. The seven HTEs are mainly in the forms of chlorides and oxides. There is an obvious relationship between the occurrence forms and simulated existence form of HTEs. SiO2 and CaCO3 are the major mineral components in the three ashes, while SA also contains chlorine-containing compounds which are easily leached out. The risk assessment code and soluble ratio show that HTEs in SA are more leachable than BA and HA, where Cd, Pb and Ni need to be addressed to reduce their impact on soil or water during subsequent landfill treatment of SA.