Abstract
In this work, it is shown that radio-frequency pulse trains designed for total correlation nuclear magnetic resonance spectroscopy can mediate inter-molecular transfer of phase coherence from one spin species to another by the dipolar field. In contrast to previous studies (where short pulses interleaved with long free precession delays were used), here the transverse component of the dipolar field plays an important role. The transfer is so efficient that signal intensities close to those of a single pulse experiment can be achieved. The results are rationalized by numerical simulations that take into account relaxation and diffusion.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
