Abstract
In the title compound, [RhCl(C21H21P)2(CO)], the coordination geometry around the RhI atom is slightly distorted square-planar with the phosphane ligands in trans positions with respect to each other. The chloride and carbonyl ligands show positional disorder, and the RhI atom lies on a center of inversion. The effective cone angle ΘE for the title compound is 169.0 (3)°. There are no significant intermolecular interactions.
Highlights
In the title compound, [RhCl(C21H21P)2(CO)], the coordination geometry around the RhI atom is slightly distorted square-planar with the phosphane ligands in trans positions with respect to each other
The chloride and carbonyl ligands show positional disorder, and the RhI atom lies on a center of inversion
Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: PV2465)
Summary
Key indicators: single-crystal X-ray study; T = 100 K; mean (C–C) = 0.005 A; disorder in main residue; R factor = 0.049; wR factor = 0.143; data-to-parameter ratio = 19.1. Crystal data [RhCl(C21H21P)2(CO)] Mr = 775.07 Monoclinic, P21=n a = 10.6440 (14) Ab = 10.9464 (15) Ac = 15.605 (2) A = 93.102 (5)
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