Abstract
In the title compound, [Cu(NO3)2(C5H6N2)4], the CuII ion is located on an inversion centre. It features a Jahn–Teller-distorted octahedral coordination geometry, defined by four N atoms of four 1-vinylimidazole ligands in the equatorial plane and two nitrate O atoms in the axial positions. The nitrate anion is disordered over two sets of sites in a 0.801 (6):0.199 (6) ratio. In the crystal, the complex molecules are linked by weak intermolecular C—H⋯O and C—H⋯π interactions.
Highlights
In the title compound, [Cu(NO3)2(C5H6N2)4], the CuII ion is located on an inversion centre
The nitrate anion is disordered over two sets of sites in a 0.801 (6): 0.199 (6) ratio
We report here the crystal structure of the title compound, [Cu(C5H6N2)4(NO3)2], a mixed-ligand CuII complex, (I)
Summary
Kilis 7 Aralık University, Vocational High School of Health Services, Department of Opticianry, 79000 Kilis, Turkey, bOndokuz Mayıs University, Arts and Sciences Faculty, Department of Chemistry, 55139 Samsun, Turkey, and cGiresun University, Arts and Sciences Faculty, Department of Chemistry, 28000 Giresun, Turkey Key indicators: single-crystal X-ray study; T = 296 K; mean (C–C) = 0.004 Å; disorder in main residue; R factor = 0.041; wR factor = 0.109; data-to-parameter ratio = 19.3.
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