Abstract
In the title compound, [Mn(NO3)2(C12H8N2)2], the MnII atom lies on a twofold rotation axis, and is six-coordinated in a distorted trans-N4O2 octahedral environment by four N atoms from two 1,10-phenanthroline ligands and two O atoms from two nitrate anions. The nitrate anion is disordered about a twofold rotation axis with fixed occupancy factors of 0.5. In the crystal, molecules are linked by weak C—H⋯O hydrogen bonds and π–π stacking interactions [centroid–centroid distance = 4.088 (5) Å] into a three-dimensional supramolecular network.
Highlights
In the title compound, [Mn(NO3)2(C12H8N2)2], the MnII atom lies on a twofold rotation axis, and is six-coordinated in a distorted trans-N4O2 octahedral environment by four N atoms from two 1,10-phenanthroline ligands and two O atoms from two nitrate anions
The nitrate anion is disordered about a twofold rotation axis with fixed occupancy factors of 0.5
Molecules are linked by weak C—H O hydrogen bonds and – stacking interactions [centroid–centroid distance = 4.088 (5) Å] into a three-dimensional supramolecular network
Summary
Hardingb and Chaveng Pakawatchaic a Department of Chemistry, Faculty of Science, Naresuan University, Muang, Phitsanulok 65000, Thailand, bMolecular Technology Research Unit, Department of Chemistry, Walailak University, Nakhon Si Thammarat 80161, Thailand, and c. Key indicators: single-crystal X-ray study; T = 298 K; mean (C–C) = 0.003 Å; disorder in main residue; R factor = 0.045; wR factor = 0.101; data-to-parameter ratio = 13.5
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