Abstract
The endo‐7‐(aminomethyl)bicyclo[3.3.1]nonan‐3‐ones 1–4 with a primary, secondary, or tertiary amino group have been synthesized, and their tendency to form the corresponding tricyclic amino carbinols has been investigated by theoretical (MMX, AM1) and experimental (PE, 13C‐NMR spectroscopy) methods. Comparison of the characteristic spectroscopic properties of 1–4 with those of the isochromophoric monofunctional compounds 7–11 indicates that 1 and 2 form mixtures with the tricyclic isomers 5 and 6, respectively, whereas 3 and 4 show no interactions between the amino and the carbonyl group in the solely present bicyclic structures.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
