Abstract
An overview on the construction of polycyclic natural productsby use of transannulation reactions across medium and large ringsis presented. 1 Introduction 2 Diels-Alder Cyclisations 2.1 10-Membered Rings 2.2 12-Membered Rings 2.3 13-Membered Rings 2.4 15-Membered Rings 2.5 16-Membered Rings 2.6 19-Membered Rings 2.7 22-Membered Rings 3 Aldol Cyclisations 3.1 8-Membered Rings 3.2 22-Membered Rings 4 Anionic Cyclisations 4.1 8-Membered Rings 4.2 10-Membered Rings 4.3 12-Membered Rings 5 Pericyclic Reactions 5.1 10-Membered Rings 5.2 12-Membered Rings 5.3 14-Membered Rings 6 Cationic Cyclisations 6.1 8-Membered Rings 6.2 9-Membered Rings 6.3 10-Membered Rings 6.4 11-Membered Rings 6.5 12-Membered Rings 6.6 13-Membered Rings 7 Radical Cyclisations 7.1 8-Membered Rings 7.2 9-Membered Rings 7.3 10-Membered Rings 7.4 11-Membered Rings 7.5 12-Membered Rings 7.6 14-Membered Rings 8 Miscellaneous Transannular Reactions 8.1 8-Membered Rings 8.2 9-Membered Rings 8.3 11-Membered Rings 9 Conclusions
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