Abstract

Abstract Imidazole(Im) or its derivatives react with Co(CNSe)2 and dimethylglyoxime (DH2) in EtOH in the presence of air to form mixed-ligand complexes of coba lt(III) of the type trans-[Co(DH)2(SeCN)(Im)]. These are non-electrolytic in DMF and Me OH and IR spectre provide evidence for the trans-structure as well as for the coordination of the selenocyenate ion through the Se-end.

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