Abstract
In the title organoplatinum(II) complex, [PtCl2(C5H5N)(C11H14O2)], the methyleugenol ligand only coordinates to the PtIIatom through the ethylenic double bond. The coordination is completed by the N atom of the pyridine ligand and two Cl atoms positionedtranswith respect to each other. The pyridine and benzene rings are inclined to one another by 68.6 (2)°. In the crystal, molecules are linkedviaa number of C—H...Cl and C—H...O hydrogen bonds, forming sheets parallel to thebcplane.
Highlights
In the title organoplatinum(II) complex, [PtCl2(C5H5N)(C11H14O2)], the methyleugenol ligand only coordinates to the PtII atom through the ethylenic double bond
The coordination is completed by the N atom of the pyridine ligand and two Cl atoms positioned trans with respect to each other
Molecules are linked via a number of C—HÁ Á ÁCl and C—HÁ Á ÁO hydrogen bonds, forming sheets parallel to the bc plane
Summary
The synthesis of the title complex has been reported elsewhere (Da, Chi et al, 2015). Atoms Pt1, Cl2 and Cl3 are disordered over two sets of sites (A/B) with final occupancies of 0.59 (4) and 0.41 (4)
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