Abstract
In the crystals of trans-diaquabis(1,1,1,5,5,5-hexafluoropentane-2,4-dionato-O,O')manganese(II) monohydrate, [Mn(C5HF6O2)2(H2O)2].H2O, the Mn atom and all three water molecules lie on a crystallographic mirror plane. Two of the water molecules are coordinated to the Mn atom in a trans geometry and the third links the structure into hydrogen-bonded sheets. The two planar hexafluoroacetylacetonato ligands related by the mirror plane form a dihedral angle of 41.6 (2)° with one another. One CF3 group displayed significant disorder.
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