Abstract

The MnII atom in the title compound, [Mn(CH3COO)2(C4H5N3)2(H2O)2]·2H2O, is situated on a center of inversion and shows an octa­hedral coordination polyhedron made up by four O atoms and two N atoms. The octa­hedron is somewhat tetra­gonally distorted owing to the longer Mn—N bond [2.323 (3) Å]. The mononuclear complex mol­ecule and uncoordinated water mol­ecules are linked by O—H⋯N, N—H⋯O and O—H⋯O hydrogen bonds, generating a three-dimensional network.

Highlights

  • Key Laboratory of Functional Inorganic Material Chemistry, Ministry of Education, Heilongjiang University, Harbin 150080, People’s Republic of China, and b

  • The octahedron is somewhat tetragonally distorted owing to the longer Mn—N bond

  • The mononuclear complex molecule and uncoordinated water molecules are linked by O—H N, N—H O and O—H O hydrogen bonds, generating a three-dimensional network

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Summary

Shan Gaoa and Seik Weng Ngb*

Key Laboratory of Functional Inorganic Material Chemistry, Ministry of Education, Heilongjiang University, Harbin 150080, People’s Republic of China, and b.

Data collection
Related literature
This work was supported by the Key Project of the Natural
Shan Gao and Seik Weng Ng
Graphite monochromator ω scans

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