Abstract
The MnII atom in the title compound, [Mn(CH3COO)2(C4H5N3)2(H2O)2]·2H2O, is situated on a center of inversion and shows an octahedral coordination polyhedron made up by four O atoms and two N atoms. The octahedron is somewhat tetragonally distorted owing to the longer Mn—N bond [2.323 (3) Å]. The mononuclear complex molecule and uncoordinated water molecules are linked by O—H⋯N, N—H⋯O and O—H⋯O hydrogen bonds, generating a three-dimensional network.
Highlights
Key Laboratory of Functional Inorganic Material Chemistry, Ministry of Education, Heilongjiang University, Harbin 150080, People’s Republic of China, and b
The octahedron is somewhat tetragonally distorted owing to the longer Mn—N bond
The mononuclear complex molecule and uncoordinated water molecules are linked by O—H N, N—H O and O—H O hydrogen bonds, generating a three-dimensional network
Summary
Key Laboratory of Functional Inorganic Material Chemistry, Ministry of Education, Heilongjiang University, Harbin 150080, People’s Republic of China, and b.
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