Abstract
The diazide platinum(II) complex, [Pt(N3)2(PPh3)2], reacts with 4-FC6H4CN under microwave irradiation to give the corresponding neutral title bis(tetrazolate) complex trans-[Pt(N4CR)2(PPh3)2] or [Pt(C7H4FN4)2(C18H15P)2]. The PtII atom lies on a crystallographic inversion centre and is coordinated by two N atoms and two P atoms in a slightly distorted square-planar environment. The unique tetrazolate ring is essentially planar and the corresponding C...;N and N...;N bond distances lie in the range 1.317 (3)–1.349 (3) Å.
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