Abstract
The ligand 1,3-bis(3-dimethylarsinopropylthio)propane, L, forms MLX 2 (M Pd, Pt; X Cl, Br, I), which are pentacoordinate [MLX]X in the solid state and in nitromethane and planar trans-[MLX 2], containing a trans-chelating diarsine ligand in dichloromethane; these are the first examples of a potentially tetradentate ligand acting as a trans-chelating bidentate.
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