Abstract
The transfer of oxygen from water to oxygen in the uv photolysis of O3–H2O mixtures is studied as a function of the ozone and water vapor pressures using 18O-labeled H2O. It is shown that deactivation of the active species is generally competitive with the ordinary chemical reactions these species undergo. It is also shown that the reaction of O1D with H2O is about four times slower than its reaction with O3. The quantum yields at different O3 and H2O pressures are calculated from the exchange data. Some preliminary experiments on the exchange of O1D with N2O and in somewhat more detail on the CO2–O2 exchange during the uv decomposition of O3 are also reported.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
