Trace element contamination in soils surrounding the open-cast coal mines of eastern Raniganj basin, India.

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Trace element pollution of soils surrounding coal-mining areas affects the health of local communities. The increasing coal-mining and associated activities in the Raniganj basin (east India) have led to increased soil concentration of certain trace elements. To quantify the elevated trace element (TE) concentrations in the soil surrounding coal-mining areas, 83 surface soil, coal, and shale samples were collected from open-cast mining areas of the eastern Raniganj basin. The soils present are sandy silt, silty sand, and silty in nature, but almost no clay. They are acidic (pH = 4.3) to slightly alkaline (pH = 7.9) with a mean electrical conductivity (EC) of 340.45µS/cm and a mean total organic carbon (TOC) of 1.80%. The northern and western parts of the study area were found to be highly polluted by certain metallic trace elements. The relevant environmental indices, geoaccumulation index (Igeo), contamination factors (CF), enrichment factors (EF), and pollution load index (PLI) were calculated and assessed. Analysis revealed that Cr was highly enriched in these soil samples, followed by Pb, Co, Cu, Cd, Fe, Ni, Mn, Zn, As, and Al. Geostatistical analyses (correlation coefficients and principal component analysis) indicated that the occurrence of some trace elements (Al, Cd, Co, Cu, Fe, Mn, Ni, and Zn) is most likely linked to the various coal-mining operations in the study area. However, the anomalous Cr and Pb distributions are likely influenced by other anthropogenic, mainly industrial, inputs besides coal mining. These results justify the adoption of rigorous soil monitoring programs in the vicinity of coal-mining areas, to identify pollution hotspots and to develop strategies to reduce or mitigate such environmentally damaging pollution.