Abstract

Vibrationally resolved threshold photoelectrons in coincidence (TPEsCO) spectra of the X 3Σ − and a 1Δ states of HCl 2+ and DCl 2+ are compared with ab initio simulations. The four resonances observed in the TPEsCO spectra of both the X 3Σ − and a 1Δ states of HCl 2+ are assigned as three quasi-bound vibrational levels and one continuum resonance with an energy greater than the potential barrier maximum. The four clearly identified resonances observed in the TPEsCO spectra of both the X 3Σ − and a 1Δ states of DCl 2+ are assigned as quasi-bound vibrational levels.

Full Text
Published version (Free)

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call