Abstract

This work assesses the environmental impact from chemical emissions due to military tests and routine activities in the area occupied by the Italian Inter-force Test Range (PISQ), located at Salto di Quirra, Sardinia, Italy. After reviewing the military activities carried out at PISQ, such as rocket launching, blasting and armament destruction, projectile and mortar fire impact, the associated pollution is evaluated. Chemical analyses were performed by means of Scanning Electronic Microscopy and Energy Dispersion Spectrometry on biotic and abiotic matrices. Residues of Rb, Tl, W, Ti and Al were found in matrices collected in the PISQ areas and environs. A review of experimental data on air, water, soil, milk, forage and animal tissues obtained by various Public Agencies of Sardinia proved that toxic element residues often exceeded the legal limits. PM10 and PM2.5 air concentrations also exceeded the legal limits after military blasting. Cd and Pb contents in the liver and kidneys of sheep living in farms at PISQ and in control farms that were located more than 20 km away from PISQ were higher than the legal limits. This work was performed to investigate concentration of xenobiotics in ecosystems emitted from PISQ activities. This assessment could be useful to focus future epidemiological studies carried out in PISQ and its neighbouring areas.

Highlights

  • With BAS-SIC (Environmental and Health Safety Lab.), ENEA-Casaccia, Rome 00123, These authors contributed to this work

  • Rb residues found by means of Scanning Electronic Microscopy (SEM) and Energy dispersive spectroscopy (EDS) analytical methodology probably derived from the following military applications: electronic warfare, telemetry and the linked atomic clock used to improve missile guidance

  • Elements and compounds were detected in several abiotic and biotic matrices associated with anthropic activities, likely military ones

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Summary

Introduction

With BAS-SIC (Environmental and Health Safety Lab.), ENEA-Casaccia, Rome 00123, These authors contributed to this work. Residues of Rb, Tl, W, Ti and Al were found in matrices collected in the PISQ areas and environs. A review of experimental data on air, water, soil, milk, forage and animal tissues obtained by various Public Agencies of Sardinia proved that toxic element residues often exceeded the legal limits. This work was performed to investigate concentration of xenobiotics in ecosystems emitted from PISQ activities. This assessment could be useful to focus future epidemiological studies carried out in PISQ and its neighbouring areas. Public data reveal that environmentally hazardous military activities in USA have generated on average a ton of toxic waste per minute during the last eight years, making them the largest source of pollution in the USA [1]. The U.S Army Corps of Engineers has stored waste coming from the production of nerve gas and pesticides during the Second World War and the Vietnam War era at the

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