Abstract
Double nucleophilic aromatic substitution reactions between N-substituted ( ν 6-1,2-dichlorobenzene)RuCp + salts and substituted 1,2-benzenediols have been carried out under mild conditions to prepare N-substituted ( ν 6-dibenzo[ b, e][1,4]dioxin)ruthenium(II)) complexes. The dibenzodioxin ligands were subsequently liberated to photolysis, with radiation from a sunlamp or from a medium pressure Hg lamp (300 nm).
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