Towards improved antifouling: Exploring xanthan gum hydrogel coatings

Abstract

This study explored xanthan gum hydrogel coatings as an approach to more environmental friendly fouling control strategies. Xanthan gum served as a filler in a conventional rosin/acrylic coating matrix, leading to the formation of a 150 μm thick gel layer on the coating surface upon seawater exposure. While biocide-free xanthan hydrogel coatings did not have significant antifouling capabilities, a synergistic effect between hydrogel and cuprous oxide was observed. During field tests at the CoaST Maritime Test Center (CMTC), it was found that the cuprous oxide concentration could be reduced by at least 50 wt% for the hydrogel coating without compromising the antifouling performance. Two possible causes were identified. First, the hydrogel coating could maintain a higher release rate over a prolonged period and second, the hydrogel was able to accumulate Cu2+, increasing retention time on the surface, creating a hostile environment. A synergistic enhancement in gel strength, yield point, and flow point was observed when xanthan was combined with konjac mannan. While promising for static applications, the rheological assessments of the different gels highlighted challenges for the application in dynamic settings like moving ships.