Abstract
Preparation des monomeres C 4 H 3 SR (R=CH 2 OPh-PhCN (1), OCH 2 CH 2 OCH 2 Ph-PhCN, CH 2 CH 2 Se-TTF, CH 2 CH 2 OCO-TTF (5), OCH 2 CH 2 OCO-TTF (TTF=tetrathiafulvalene), CH 2 NHCO-(CH 2 ) 5 OPh-PhCN. La polymerisation electrolytique du compose (1) donne un polythiophene de conductivite 1,5-10 −2 S/cm et presentant des transitions thermiques compatibles avec un comportement cristallin liquide. Le monomere (5) est aussi polymerise
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