Toward a Quantitative Correlation between Microstructure and DSSC Efficiency: A Case Study of TiO2–xNx Nanoparticles in a Disordered Mesoporous Framework

Abstract

The efficiency (η) of a dye-sensitized solar cell (DSSC) depends on various parameters, the critical factors being a fast charge carrier transport and a slow rate of electron–hole recombination. The present article describes a simple combustion synthesis method to prepare TiO2–xNx with following four important features that directly influences η: (1) a disordered mesoporous structural framework with high surface area to give high dye-loading and a small diffusion length for charge carriers allowing rapid movement to the surface; (2) electrically interconnected nanocrystalline TiO2–xNx particles with good necking and predominant (101) anatase facets to minimize electron–hole recombination; (3) low charge storage capacity in the titania framework; and (4) surface unsaturation assisting all the above factors. The pseudo-three-dimensional nature of mesoporous TiO2–xNx with the above features demonstrates the importance of textural features, and porosity allows faster diffusion of charge carriers to surface an...