Toughened PS/LDPE/SEBS/xGnP ternary composites: morphology, mechanical and viscoelastic properties

Abstract

In this work, we have developed super tough ternary polymer blends and composites composed of polystyrene (PS), low-density polyethylene (LDPE), polystyrene-block-poly(ethylene-ran-butylene)-block-polystyrene (SEBS) and exfoliated graphene nanoplatelets (xGnP). A 50/50 composition of PS and LDPE was selected for making the binary blend. The addition of xGnP in the binary blend reduces the tensile strength, elongation at break and tensile toughness considerably due to the unfavorable interactions existing between PS, LDPE, and xGnP. On the other hand, the mechanical properties of PS/LDPE binary blends are considerably improved by the addition of SEBS at the expense of modulus. The best results were obtained for a 33/33/33 (PS/LDPE/SEBS) composition. Further, different concentrations of xGnP were incorporated in the ternary blend with 33/33/33 composition. Interestingly, the composites show a significant improvement in mechanical properties especially for 2.91 wt% xGnP modified ternary blend. The DMA studies revealed that the stress with in the ternary composites are minimum when compared with binary blends and their composites. The variation in the phase morphology of the binary blends by the addition of SEBS and xGnP is responsible for the dramatic changes in mechanical and viscoelastic properties. This study validates large improvement in mechanical properties of the PS/LDPE polymer blends by the careful selection of SEBS and xGnP.