Total synthesis of (+)-varitriol and (+)-6′- epi-varitriol

K Vamshikrishna,P Srihari

doi:10.1016/j.tet.2011.12.008

Total synthesis of (+)-varitriol and (+)-6′- epi-varitriol

K Vamshikrishna, P Srihari

https://doi.org/10.1016/j.tet.2011.12.008

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Journal: Tetrahedron	Publication Date: Dec 9, 2011
Citations: 22

Affiliation: Indian Institute of Chemical Technology

#Corey Chaykovsky Reaction #O-anisic Acid + Show 3 more

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Abstract

Total synthesis of (+)-varitriol and its C6′-epimer have been achieved starting from commercially available d-(−)-ribose and o-anisic acid. The key steps involved are Corey Chaykovsky reaction, triethylamine mediated epimerization, and an olefin cross-metathesis.

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