Abstract
Chemoselective by design: The first total synthesis of members of the axinellamine/palau'amine/massadine class of pyrrole–imidazole alkaloids features unconventional transformations on completely unprotected polyamino and hydroxylated substrates and a new method for chemoselective oxidations in such settings. Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2008/z801138_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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