Abstract
The sensitivity of multiple quantum NMR transitions to magnetic field inhomogeneity and the relative phases and amplitudes of multiple quantum lines are discussed. The technique of total spin coherence transfer echo spectroscopy (TSCTES) is described and experimentally demonstrated. The TSCTES method allows multiple quantum spectra to be obtained which are free of inhomogeneous magnet broadening, yet remain sensitive to spin–spin couplings and chemical shift differences. The method takes advantage of the properties of the total spin coherence, the unique transition between the extreme eigenstates of a coupled spin system. Experimental results are reported for partially oriented acetaldehyde and are analyzed in terms of irreducible tensor operators. Limitations on the method and extensions to heteronuclear spin systems are also discussed.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
