Abstract

Femtosecond-picosecond time-resolved absorption spectral measurements on 9,9′-bianthryl in polar alkanenitrile solvents revealed that the rise curve of the charge-transfer (CT) state contained components with rise times considerably longer than the solvent τ L , which indicated the importance of the torsional relaxation from the approximately perpendicular to the tilted configuration in the CT state formation.

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