Abstract
DARC topological analysis (DTA) has been applied to Kováts retention indices for a series of 84 linear alkenes up to tetradecenes studied by gas-liquid chromatography on squalane at 100 °C. The topology-information diagram gives information at the skeletal carbon atom level of the alkene molecules. Very small structural effects are detected and discussed on a statistical basis. This set of n-alkenes constitutes a good model for testing the interpretative and physico-chemical potentialities of DTA in order to establish a set of precise reference data for higher n-olefins of petrochemical interest.
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