Tomographic Positron Annihilation Lifetime Spectroscopy

Abstract

Positron annihilation lifetime spectroscopy serves as a perfect tool for studies of open-volume defects in solid materials such as vacancies, vacancy agglomerates, and dislocations. Moreover, structures in porous media can be investigated ranging from 0.3 nm to 30 nm employing the variation of the Positronium lifetime with the pore size. While lifetime measurements close to the material's surface can be performed at positron-beam installations bulk materials, fluids, bio-materials or composite structures cannot or only destructively accessed by positron beams. Targeting those problems, a new method of non-destructive positron annihilation lifetime spectroscopy has been developed which features even a 3-dimensional tomographic reconstruction of the spatial lifetime distribution. A beam of intense bremsstrahlung is provided by the superconducting electron linear accelerator ELBE (Electron Linear Accelerator with high Brilliance and low Emittance) at Helmholtz-Zentrum Dresden-Rossendorf. Since the generation of bremsstrahlung and the transport to the sample preserves the sharp timing of the electron beam, positrons generated inside the entire sample volume by pair production feature a sharp start time stamp for lifetime studies. In addition to the existing technique of in-situ production of positrons inside large (cm3) bulk samples using high-energy photons up to 16 MeV from bremsstrahlung production, granular position-sensitive photon detectors have been employed. The detector system will be described and results for experiments using samples with increasing complexity will be presented. The Lu2SiO5:Ce scintillation crystals allow resolving the total energy to 5.1 % (root-mean-square, RMS) and the annihilation lifetime to 225 ps (RMS). 3-dimensional annihilation lifetime maps have been created in an offline-analysis employing well-known techniques from PET.