Abstract

The electronic absorption and emission spectra of COXD-Perchlorate polar laser dye in distinct organic solvents have been analyzed, to understand the relationship exhibited between absorption spectrum (λmax) and solvatochromic constants, through non-specific and specific interactions effects on the intensities, peak positions of both absorption and emission spectrum. The electronic absorption in distinct solvent exhibits a feeble and broad spectrum domain as a result of π-π* transits. Spectral regression techniques were used for the qualitative chemical analyses of a COXD-Perchlorate compound which provide an opportunity to get an insight of solvent ability to form the Hydrogen-coupling with the solute particles besides the electric dipole interactions and electrical-optical molecular parameters in the excited states. The HOMO and LUMO energy band gap suggest compound is softer and highly reactive.

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