(TM EDA)2Li4Cl4(H2O)2]·2 TMEDA: stabförmige vierkernige Li-Komplexe verknüpft durch TMEDA / [(TM EDA)2Li4Cl4(H2O)2]·2 TMEDA: Stick-Like Tetranuclear Li Complexes Connected by TMEDA

Abstract

Abstract The title compound 1 was synthesized by the reaction of LiCl with TM EDA (N,N,N′,N′- tetramethylethylendiamine) and water at 120 °C in boiling TM EDA. 1 was crystallized at - 30 °C as colorless crystals and characterized by NMR and IR spectroscopy as well as by an X-ray structure determination. 1 is a polymer in the solid state, built up by an alternating arrangement of stick-like tetranuclear Li complexes and two TMEDA molecules. The complexes and the TMEDA molecules are connected by hydrogen bridges in infinite chains.