Abstract
Neutral and cationic titanium imido complexes (R = t-Bu or SiMe3) with a triazacyclononane ligand bearing a monopendant arm have been synthesized. The structures of [Ti(NSiMe3)(L1)Cl] and [Ti(NBut)(L2)Cl]Cl are reported where HL1 = 1-(2-hydroxy-3,5-di-tert-butylbenzyl)-4,7-diisopropyl-1,4,7-triazacyclononane and L2 = 1-(2-pyridylmethyl)-4,7-diisopropyl-1,4,7-triazacyclononane.
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