Abstract
The system Ti(IV) tetra-tert-butoxide-tert-butyl hydroperoxide in mild conditions (20°C) oxidizes C-H bonds of methyl (toluene), methylene (hexane, ethylbenzene, benzyl ethyl ether), and methine (1, 1-diphenylethane, triphenylmethane) groups. The role of oxidant is played by the oxygen generated by the system. The process involves free radicals and produces hydroperoxides and Ti(IV) peroxides. The latter decompose both with preservation and decomposition of the hydrocarbon skeleton.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
