Abstract
Two dianionic amine bis(phenolate) ligands are introduced and their reactions with titanium tetra(iso-propoxide) studied; ligand 1 having a single N-donor group leads exclusively to a homoleptic Lig 2Ti type complex whereas ligand 3 having an additional N-donor on a side arm leads exclusively to a LigTi(OPr i) 2 type complex.
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