Abstract

Titania has properties that enable it to be used in a variety of applications, including self-cleaning surfaces, air and water purification systems, hydrogen evolution, and photoelectrochemical conversion. In order to improve the properties of titanium dioxide, modifications are made to obtain oxide/hybrid systems that are intended to have the properties of both components. In particular, zinc oxide, zirconia and molybdenum disulfide have been proposed as the second component of binary systems due to their antibacterial, electrochemical and photocatalytic properties. This paper presents a review of the current state of knowledge on the synthesis and practical utility of TiO2-ZnO and TiO2-ZrO2 oxide systems and TiO2-MoS2 hybrid materials. The first part focuses on the hydrothermal method; then a review is made of the literature on the synthesis of the aforementioned materials using the sol-gel method. In the last section, the literature on the electrospinning method of synthesis is reviewed. The most significant physico-chemical, structural and dispersive-morphological properties of binary hybrid systems based on TiO2 are described. A key aim of this review is to indicate the properties of TiO2-ZnO, TiO2-ZrO2 and TiO2-MoS2 hybrid systems that have the greatest importance for practical applications. The variety of utilities of titania-based hybrid materials is emphasized.

Highlights

  • Constant scientific and technological progress, as well as the desire to create environment-friendly technologies, is leading to intensive work on obtaining new-generation, functional products with strictly designed physico-chemical and dispersive-morphological properties, dedicated to specific applications. These studies focus on changing the physico-chemical features of many well-known and widely used materials. This group of substances includes oxide and hybrid materials based on titanium dioxide, which are distinguished by specific, precisely defined physico-chemical and structural properties, determined at the stage of their synthesis

  • The literature review that has been presented here reflects the search for innovative combinations of TiO2 with other materials, which may cause morphological changes in the crystalline phases of titanium dioxide and changes in its electron structure, leading to—among other things—improvement in its photocatalytic activity and spectral sensitivity

  • Studies being carried out at multiple research centers worldwide are largely focused on the choice of appropriate methods for the synthesis or modification of titanium dioxide, and on the selection of suitable components to be combined with TiO2 to produce advanced multifunctional hybrid materials

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Summary

Introduction

Constant scientific and technological progress, as well as the desire to create environment-friendly technologies, is leading to intensive work on obtaining new-generation, functional products with strictly designed physico-chemical and dispersive-morphological properties, dedicated to specific applications. These studies focus on changing the physico-chemical features of many well-known and widely used materials. This group of substances includes oxide and hybrid materials based on titanium dioxide, which are distinguished by specific, precisely defined physico-chemical and structural properties, determined at the stage of their synthesis. Technological progress is accompanied by increased interest in and Materials 2018, 11, 2295; doi:10.3390/ma11112295 www.mdpi.com/journal/materials

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