Abstract

TiO2 powder was modified by the afterglow of plasma of pure N2 or H2, and mixed N2 + H2 gas. The ion species in plasma afterglow were measured by an ion-energy analyzer. It is found that the main ion is N2+ in N2 afterglow and the yield is changed to NH4+ with a six times higher concentration, when 10% H2 was input. The modified TiO2 shows significant differences of microstructure and optical properties depending on the plasma gas used. This work enables one to find a correlation between active species in the plasma afterglow and TiO2 microstructure/optical properties.

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