Abstract
AbstractTin nanoclusters were obtained in potassium chloride crystals following the electrolytic coloration of KCl:Sn2+ and KCl: Sn2++Ca2+ crystals and thermal annealing at various temperatures and times. Electrolytic coloration of KCl:Sn2+ crystals produces electronic centers inside of samples, presumably negative metal ions of tin. Optical absorption measurements were performed on as grown sample, colored and thermal annealed samples. The behavior of the samples with Sn colloids was compared with theoretical predictions according to Mie's theory. Tin nanoclusters in KCl exhibit an absorption band with a peak at 215 nm. The structure of the nanoclusters was studied by optical absorption and transmission electron microscopy means. (© 2007 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)
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