Abstract
Solidification processes of Fe-B and Fe-C eutectic alloys have been investigated by a time-resolved synchrotron x-ray diffraction under containerless cooling conditions using a conical nozzle levitation technique. To observe relative variations of structure from the undercooled liquid to crystalline phase, we have conducted millisecond order time-resolved x-ray diffraction experiments with a two-dimensional detector. The structural variations observed during the solidification of the Fe83C17 alloy were identified as the phase transformation process expected from the Fe-C phase diagram. As for the Fe83B17 alloy, it was revealed that a metastable phase composed of Fe23B6 compound was precipitated as a primary crystalline phase from the undercooled liquid. In addition, decomposition of the metastable Fe23B6 phase showed dependence on the cooling rate of the sample. At the cooling rate of 30 K/s, the Fe23B6 phase decomposed to bcc-Fe and Fe2B phases with decreasing temperature. On the contrary, at the cooling rate of 180 K/s, the metastable Fe23B6 phase remained in spite of an appearance of the bcc-Fe phase. By comparing the primary crystalline phase between the Fe83C17 and the Fe83B17 alloys, we suggest that the formability of the metastable Cr23C6-type compound is closely related with the glass-forming ability of Fe-metalloid binary alloys.
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