Abstract

Applications of laser flash photolysis techniques are illustrated using three specific cases among many photoprocesses involving transition metal polypyridyl complexes (LL = bpy, phen or related ligands): dynamics of photoinduced formation of complexes of the type M(CO)4(LL), where M = Mo0, Cr0 or W0; dynamics of photosubstitution reactions of Ru(LL) 3 2 + and photoredox reactions of MLCT excited states of RuII(LL) 3 2+ and [ReI(CO)3(Cl)(LL)].

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