Abstract

Abstract A nozzle beam of molecular oxygen was scattered from clean and oxygen-covered Pt(111) surfaces and velocity distributions of the scattered molecules were investigated by time-of-flight (TOF) measurements. From the clean surface at a surface temperature of T s = 900 K mainly direct quasi-elastic scattering is observed whereas from the oxygen-covered surface (p(2 × 2) layer as confirmed by LEED) at T s = 300 K the TOF distribution is composed of two parts: besides some directly scattered molecules a relatively high number of molecules with a Maxwellian distribution according to T s = 300 K appears. These thermalized molecules are attributed to a trapping-desorption channel. Our results provide new and rather direct experimental proof for interpretations of angular distributions already known from literature.

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