Abstract
The time-resolved photoelectron spectrum (TRPES) of RbI molecule is simulated using the time-dependent wave-packet method. Both the normal three-photon ionization process and auto-ionization process are involved in the simulation. The calculated results show that the change of delay time will influence the shape of the photoelectron spectrum (PES), and the influence is sub- stantially due to the existence of the crossing between excited states and the strong laser field which will change the position of relevant curves.
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