Abstract

The time differential perturbed angular distribution technique has been applied to studies in synthetic diamond grown by the chemical vapor deposition method. It was found that the 19F nuclear probe used occupies only one characteristic lattice site associated with a coupling frequency of 63(3) MHz. This result represents a starkly different situation when compared with previous findings from extensive investigations on three different types of natural diamond, as well as on synthetic diamond grown under high temperature, high pressure conditions. Such comparison has revealed the role of hydrogen in the different types of diamond and its particular chemical form of occurrence. As hydrogen seems to play an important role in different methods of synthesis, these findings give a first insight into such synthesis aspects.

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