Time scales of olivine storage and transport as revealed by diffusion chronometry at Waitomokia Volcanic Complex, Auckland Volcanic Field, New Zealand

Abstract

Detailed knowledge of the pre-eruptive time scales associated with magma storage and transport is vital to improve volcanic hazard forecasting in active volcanic regions. However, quantification of the timescales of volcanic processes at mafic volcanic centres in continental intraplate settings is challenging, despite them being a source of significant hazards for human populations and infrastructure due to their limited predictability in space and time. We conducted a detailed petrological study to investigate the time scales of olivine storage and transfer throughout the eruption sequence of Waitomokia Volcanic Complex, a tuff ring and scoria cone complex in the Auckland Volcanic Field. Olivine crystal textures and compositions were determined from stratigraphically-constrained samples of the volcanic complex, from the initial phreatomagmatic phase to the final magmatic phase. Olivine crystals are typically <300 μm in length and characterised by skeletal morphologies, displaying chemical zoning in forsterite (Fo = 100*Mg/[Mg + Fe]; mol%), CaO, MnO and NiO wt% contents. We classified olivine into three major groups based on their Fo core compositions: (1) normally zoned crystals with high Fo content (Fo > 85), (2) crystals with intermediate Fo contents (84–81), and (3) reversely zoned crystals with lower Fo core content (<80). Olivine chemical zoning (diffusion) profiles were modelled in the context of a specific magmatic environment linked with changes in thermodynamic variables during storage (temperature, pressure, and oxygen fugacity). We propose that the normally zoned olivine crystals grew in one magmatic environment (ME1), which subsequently intruded into a more evolved (lower MgO) environment (ME2), where they interacted and were stored for up to 135 days before their eruption. During magma ascent to the surface, a second magma mixing event occurred between ME2 and magma within a third magmatic environment (ME3), forming reversely-zoned olivine crystals yielding notably shorter ascent times of approximately a few days. The rocks from the opening phreatomagmatic phase of the eruption show a larger range in olivine group types compared to the final magmatic phase, where those from the deeper ME1 are more abundant. The short time scales of magma transport obtained in our study, on the order of days to months, should be informative of the warning times that may be encountered between the onset of volcanic unrest and an eruption in the Auckland Volcanic Field.