Abstract
The average internal energy of benzylamine molecules dissociated via infrared multiple photon excitation is derived from laser induced fluorescence (LIF) measurements of [NH 2] versus time, and is 50–70 kcal mol −1 above threshold at fluences of 10–30 J cm −2. The benzyl radical is monitored by LIF and is produced vibrationally “hot”. Fluorescence lifetimes of bands in its 1 2A 2-1 2B 2 system are reported.
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