Abstract
The relaxation dynamics of hot electrons in the ${\mathit{X}}_{6}$ and ${\mathit{X}}_{7}$ satellite and upper conduction bands in GaP was directly measured by femtosecond UV-pump--IR-probe absorption spectroscopy. From a fit to the induced IR-absorption spectra the dominant scattering mechanism giving rise to the absorption at early delay times was determined to be intervalley scattering of electrons out of the ${\mathit{X}}_{7}$ upper conduction-band valley. For long delay times the dominant scattering mechanism is electron-hole scattering. Electron transport dynamics of the upper conduction band of GaP has been time resolved.
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