Time-resolved dynamics of two-channel molecular systems in cw laser fields: Wave-packet construction in the Floquet formalism.

Abstract

The description of the wave-packet time-resolved dynamics in a two-channel molecular system driven by a cw laser field is considered within the time-independent Floquet representation. It is shown that, at high field intensity, the wave-packet motions are governed solely by the pair of adiabatic dressed potential-energy surfaces (PES's) associated with a single Brillouin zone. The same expressions of the wave-packet motions in terms of the adiabatic PES's are obtained within a short-time approximation, thereby furnishing a new numerical algorithm for the wave-packet propagation in a laser-driven two-channel system at any intensity. Numerical tests of this algorithm are presented. The numerical results establish unambiguously the adiabaticity of nuclear motions at high field intensities.